arrange the following in increasing order of acidic strength benzoic acid , P nitrobenzoic acid , P methyl benzoic acid , give reason
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Hello dear your answer is given below...
acidic strength....
p-nitro benzoic acid > benzoic acid > p-methyl benzoic acid
- Explanation :
=> nitro group (-NO2) is electron withdrawing group which decreas electron density on -COOH group thus, acidic strength increase...
=> methyl group (-CH3) is electron donating group which increase electron density on -COOH group thus acidic strength decrease....
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The trend is para methyl benzoic acid < benzoic acid < para nitrobenzoic acid.
Explanation:
- The acidity of an acid depends on the stability of the corresponding base.
- The benzoate ion has a resonance stability which is increased with the addition of electron withdrawing groups to benzene.
- The nitro group is an electron withdrawing group whereas the methyl is electron donating group.
- So the acidity trend is para methyl benzoic acid < benzoic acid < para nitrobenzoic acid.
For more information about acidity trend,
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