Arrange the following in order of increasing property indicated: (1) HCHO, CH3COCH3, CH3CH2CHO, C6H5CHO (toward HCN) (2) CH3CHO, CH3COCH3, CH3COOH, CH3OCH3: (boiling point)
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Answer:
All these compounds have comparable molecular masses, CH
3
CH
2
OH undergo extensive intermolecular h-bonding, thus having the highest boiling point.
CH
3
CH
2
CH
3
have weak vander waals forces thus lowest boiling point.
And in CH
3
CHO there are more dipole-dipole interactions than CH
3
OCH
3
, thus having a greater boiling point.
CH 3CH2CH 3<CH 3OCH 3 <CH 3CHO<CH 3CH 2OH
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Explanation:
CH 3CH2CH 3<CH 3OCH 3 <CH 3CHO<CH 3CH 2OH
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