Arrange the following in the increasing order of acidity:- water,ethanol, ethylene diol,glycerol
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12th
Chemistry
Alcohols, Phenols and Ethers
Chemical Reactions of Alcohols and Phenols
Arrange: water, ethanol, an...
CHEMISTRY
Arrange: water, ethanol, and phenol in increasing order of acidity and give reason for your answer.
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Increasing order of acidity is ethanol < water < phenol. The phenoxide ion obtained after the removal of a proton is stabilized by resonance whereas the ethoxide loan obtained after the removal of a proton is destabilized by +I Effect of −C
2
H
5
group. Therefore, phenol is a stronger acid than ethanol, On the other hand, ethanol is a weaker acid than water because electron releasing −C
2
H
5
- group in ethanol increases the electron density on oxygen and hence the polarity of O−H bond in ethanol decreases which results in the decreasing acidic strength
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enthanol < water < ethylene < diol<glycrrol
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