Assertion: Branched chain alkanes have lower boiling point increases.
Reason: as molecular size decreased, boiling point increases.
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Assertion: Among the isomeric alkanes, the branched chain isomers have lower boiling point than the straight chain isomers. Reason: With branching of chain surface area decreases and the vander waal forces of attraction which depend upon surface area also tend to decreases
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Both A and R are correct and R is the correct explanation of A
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