At 17°c osmotic pressure of sugar sol was 580 torr. The sol is diluted and temp is raised to 57°c osmotic pressure become 165torr the extend of dilution is
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The extent of dilution is 4 times.
Given-
- Initial temperature of sugar solution = 17 °C
- Osmotic pressure at 17 °C is = 580 torr
- Final temperature of the sugar solution = 57 °C
- Osmotic pressure at 57 °C is = 165 torr
Here,
T₁ = 290 K
π₁ = 580 torr = 580/760 mm of Hg
T₂ = 330 K
π₂ = 165 torr = 165/760 mm of Hg
We know that osmotic pressure can be given by-
π = CRT where C is the concentration, R is the universal gas constant and T is the temperature.
π₁ = C₁RT₁
π₂ = C₂RT₂
By substituting the values we get
580/760 = C₁ × R × 290 ---------(i)
165/760 = C₂ × R × 330 ----------(ii)
By dividing (i)/(ii)
580/165 = C₁/C₂ × 290/330
C₁/C₂ = 3.515/0.8788
C₁/C₂ = 3.999 ≈ 4 times
C₁ = 4 C₂
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