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Explanation:
1 mole is a specific quantity of atoms or molecules given by Avogadro's Number - 6.022 x 10^23
Thus
1 mole of C will have 6.022 x 10^23 number of atoms.
1 mole of O2 will have 6.022 x 10^23 number of molecules.
As the atoms of C available are same as molecules of O2, complete reaction will take place to for CO2.
Thus 6.022 x 10^23 numbers of molecules of CO2 will be produced when 1 mole of C reacts completely with 1 mole of O2
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