At elevated temperature around 1000 k S2-3 is the dominating species of sulphur which is paramagnetic in nature
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When temperature is raised above 1000 K, sulphur changes to vapour phase as S2 molecule. - S2 molecule contains 2 unpaired electrons in antibonding π-orbital. Thus it is paramagnetic. - Therefore, sulphur at 1000 K shows paramagnetism
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