Chemistry, asked by rajmth7394, 10 months ago

At low pressure the van der Waal’s equation is reduced to
(a) Z=pVₘ/RT=1-ap/RT
(b) Z=pVₘ/RT=1+b/RT p
(c) pVₘ = RT (d) Z = pVₘ/RT = 1 - a/RT

Answers

Answered by King99041
0

Answer:

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Answered by rashich1219
0

At low pressure the van der Waal’s equation is reduced to \bold{Z=\frac{PV_{m}}{RT}=1-\frac{a}{RTV_{m}}}

Step by step explanation:

The Vander waal equation is as follows.

                        (P+\frac{a}{V_{m}^{2}})(V_{m}-b)=RT.............................(1)

At low pressure,

Volume of the gas sufficiently high and the constant "b" is ignored in the expression -1 reduced to

                                (P+\frac{a}{V_{m}^{2}})(V_{m})=RT

                                     PV_{m}+\frac{a}{V_{m}}=RT

                                     \Rightarrow PV_{m}=RT-\frac{a}{V_{m}}

                                  \bold{Z=\frac{PV_{m}}{RT}=1-\frac{a}{RTV_{m}}}

Therefore, At low pressure the van der Waal’s equation is reduced to \bold{Z=\frac{PV_{m}}{RT}=1-\frac{a}{RTV_{m}}}.

Hence, correct option is "d".

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