ATl+|Tl couple was prepared by
saturating 0.10M - KBr with TIBr and
allowing Tl+ ions form the insoluble
bromide to equilibrate. This couple was
observed to have a potential -0.444V with
respect to PB2+|Pb couple in which Pb2+
was 0.10 M. What is the K sp of TlBr. [Given
Pb2+ Pb
= -0.336V,
-0.126V, E
log2.5 = 0.4, 2.303RT/F = 0.06]
:E
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