Atomic orbital is the region in which there is maximum probability of finding electron
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In 1926, when the wave mechanical model of the atom was made, Schrodinger had published the Schrodinger equation. On solving this, you can get the probability density of an electron at any distance and angle from the nucleus.
On solving this equation, the regions of space that have 90–95% probability of find an electron are found. These were coined orbitals.
Thus, Orbitals have maximum probability of finding an electron by definition
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