(b) Discuss the variation of effective
nuclear charge in periodic table.
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The periodic table tendency for effective nuclear charge:
Increase across a period (due to increasing nuclear charge with no accompanying increase in shielding effect).
Decrease down a group (although nuclear charge increases down a group, shielding effect more than counters its effect).
Explanation:
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Increase across a period (due to increasing nuclear charge with no accompaning increase in shielding effect). Decrease down a group (although nuclear charge increases down a group shielding effect more than counters its effect.
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