b)MnO- + I- = MnO 2 + I2
Answers
Answer:
The unbalanced chemical equation is
MnO
4
−
(aq)+I
−
(aq)→MnO
2
(s)+I
2
(s)
The oxidation half reaction is
I
−
(aq)→I
2
(s)
The reduction half reaction is
MnO
4
−
(aq)→MnO
2
(aq)
Balance I atoms and charges in the oxidation half reaction.
2I
−
(aq)→I
2
(s)+2e
−
In the reduction half reaction, the oxidation number of Mn changes from +7 to +4. Hence, add 3 electrons to reactant side of the reaction.
MnO
4
−
(aq)+3e
−
→MnO
2
(aq)
Balance charge in the reduction half reaction by adding 4 hydroxide
ions to product side.
MnO
4
−
(aq)+3e
−
→MnO
2
(aq)+4OH
−
To balance O atoms, add 2 water molecules to reactant side.
MnO
4
−
(aq)+3e
−
+2H
2
O→MnO
2
(aq)+4OH
−
To equalize the number of electrons, multiply the oxidation half reaction by 3 and multiply the reduction half reaction by 2.
6I
−
(aq)→3I
2
(s)+6e
−
2MnO
4
−
(aq)+6e
−
+4H
2
O→2MnO
2
(aq)+8OH
−
Add two half cell reactions to obtain the balanced equation.
2MnO
4
−
(aq)+6I
−
(aq)+4H
2
O
2
(l)→2MnO
2
(s)+3I
2
(s)+8OH
−
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