Balanced chemical reaction for sodium nitrate is heated
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Sodium nitrate when heated to about 500°C will give Sodium nitrite and Oxygen gas.
But as we increase the temperature to 800°C, the formed Sodium nitrite will further decompose to form Sodium oxide and Nitrogen gas.
Heating at 500°C
2 NaNO₃ → 2 NaNO₂ + O₂
Heating till 800°C
4 NaNO₃ → 2 Na₂O + 2 N₂ + 5 O₂
Hope it helps!
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