Barium chloride reacts with aluminium sulphate to give aluminium chloride and a precise of barium sulphate
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bacl2 + Al2(SO4)3 - AlCl3 + BaSO4
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3BaCl2(s) + Al2(SO4)3(s) ➝ 3BaSO4 + 2Al2Cl3(s)
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