Chemistry, asked by Akhileshku5879, 1 year ago

benzoic acid is stronger than acetic acid

Answers

Answered by RaviKumarNaharwal
39
Benzene is an electron withdrawing group and hence it creates an addition partial positive charge on the Oxygen Atom present in the -OH group through propagation thus increasing its electron withdrawing power.

But no such effect exists in acetic acid. In fact the -CH3 (methyl group) is an electron donating group which reduces the electron withdrawing power of Oxygen Atom.

Hence Benzoic acid is more acidic than Acetic acid.

Answered by ManuKushwah
22
because the negative charge on benzoic acid is stable due to -I of benzene but the negative charge of acetic acid is destabilised due to the +I effect of CH3
(the negative charge is after removing the hydrogen at COOH group)
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