Question

Benzyl alcohol is obtained from benzaldehyde by:
(a) Perkin’s reaction
(b) Wurtz reaction
(c) Cannizzaro’s reaction
(d) Claisen’s reaction

Answer 1

Benzyl alcohol is obtained from benzaldehyde by:

(c) Cannizzaro's reaction.

Answer 2

Benzyl alcohol is obtained from benzaldehyde by: Cannizzaro’s reaction

Explanation:

• The Cannizzaro reaction is when a non-enolizable aldehyde reacts with itself in a strong base, such as sodium hydroxide (NaOH), to form a carboxylic acid and an alcohol. Two of the most common non-enolizable aldehydes are formaldehyde and benzaldehyde.
• The crossed-Cannizaro reaction yields neopentylglycol which is being used in polyesters (for resins used in airplane or boat manufacturing), varnish coatings, synthetic lubricants, and plasticizers. The neopentyl structure provides excellent resistance to light, heat and hydrolysis.

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