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Contents Home Bookshelves Inorganic Chemistry Map: Inorganic Chemistry (Housecroft) 4: Experimental Techniques 4.10: Mossbauer Spectroscopy Expand/collapse global location
4.10B: What Can Isomer Shift Data Tell Us?
Last updatedJun 6, 2019
4.10A: The Technique of Mossbauer Spectroscopy
4.11: Structure Determination - Diffraction Methods
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Among the drawbacks of the technique are the limited number of gamma ray sources and the requirement that samples be solid in order to eliminate the recoil of the nucleus. Mössbauer spectroscopy is unique in its sensitivity to subtle changes in the chemical environment of the nucleus including oxidation state changes, the effect of different ligands on a particular atom, and the magnetic environment of the sample.
As an analytical tool Mössbauer spectroscopy has been especially useful in the field of geology for identifying the composition of iron-containing specimens including meteors and moon rocks. In situ data collection of Mössbauer spectra has also been carried out on iron rich rocks on Mars.
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