Boiling and melting point of a substance are indication of the forces of attraction between the particles
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Answer:
Explanation:
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CONTENTS
INTRODUCTORY CHEMISTRY – 1ST CANADIAN EDITION
Chapter 10. Solids and Liquids
Phase Transitions: Melting, Boiling, and Subliming
David W. Ball and Jessie A. Key
Learning Objectives
Describe what happens during a phase change.
Calculate the energy change needed for a phase change.
Substances can change phase—often because of a temperature change. At low temperatures, most substances are solid; as the temperature increases, they become liquid; at higher temperatures still, they become gaseous.
The process of a solid becoming a liquid is called melting. (an older term that you may see sometimes is fusion). The opposite process, a liquid becoming a solid, is called solidification. For any pure substance, the temperature at which melting occurs—known as the melting point—is a characteristic of that substance. It requires energy for a solid to melt into a liquid. Every pure substance has a certain amount of energy it needs to change from a solid to a liquid. This amount is called the enthalpy of fusion (or heat of fusion) of the substance, represented as ΔHfus. Some ΔHfus values are listed in Table 10.2 “Enthalpies of Fusion for Various Substances”; it is assumed that these values are for the melting point of the substance. Note that the unit of ΔHfus is kilojoules per mole, so we need to know the quantity of material to know how much energy is involved. The ΔHfus is always tabulated as a positive number. However, it can be used for both the melting and the solidification processes as long as you keep in mind that melting is always endothermic (so ΔH will be positive), while solidification is always exothermic (so ΔH will be negative).
Explanation:
Intermolecular forces (IMFs) can be used to predict relative boiling points. The stronger the IMFs, the lower the vapor pressure of the substance and the higher the boiling point. Therefore, we can compare the relative strengths of the IMFs of the compounds to predict their relative boiling points.