Boiling point of water at 750 mm is 96.63°C. How
much sucrose is to be added to 500g of water such
that it boils at 100°C ? Kb = 0.52 K kg/mol.
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Given, △T
b
=100−99.63=0.37
o
;K
b
=0.52
Mass of water =500 g
Let x gm of sucrose be added.
Molar mass of sucrose =342 g mol
−1
Molality (M)=
342×500
x×1000
=
171
x
△T
b
=K
b
×m
0.37=0.52×
171
x
x=121.67 gm
Therefore, 121.67 gm of sucrose must be added.
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