Question

bromination of m-nitrobromobenzene gives​

Answer 1

Nitrobenzene reacts with Br 2 in the presence of FeBr3 to give m-bromonitrobenzene as the major product.The best reason for the formation of m-bromonitrobenzene as the major product is as given below.

The σ-complex formed by the attack of Br+

at the meta position is the least destabilized and the most stable among the three σ-complexes. Hence, the nitro group acts as meta directing group. It deactivates the ring.

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