Burning a sample of a hydrocarbon gas gives 3.38g CO2 &0.690H2O.a volume of 10l of hydrocarbon weighs 11.6grams.calcukate the molecular formula of this hydrocarbon
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A hydrocarbon contains 80% of carbon.
means, mass percentage of C = 80%
then mass percentage of H = 20% .
find percentage atomic mass ratio,
for C ⇒80/12 = 20/3
for H ⇒20/1 = 20
find simple ratio of given numerical value.
C : H = 20/3 : 20 = 1 : 3
so, empirical formula of hydrogen is CH_3CH3
as it is given, vapor density of hydrogen is 30.
so, molar mass of hydrogen = 2 × vapor density
= 2 × 30 = 60 g/mol.
now, molecular mass = n × mass of empirical formula
60 = n (12 × 1 + 1 × 3)
n = 4
hence, molecular formula of hydrocarbon is C_4H_{12}C4H12
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