Question

By whom copper was used first time​

Answer 1

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The dating of this epoch, known as the Bronze Age is different for the various civilizations but most probably bronze was used for the first time in Mesopotamia or Egypt. The ancient Egyptians obtained bronze alloys discovering that it was easier to cast copper if a small quantity of tin was added to it.

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Answer 2

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Copper was first used by man over 10,000 years ago.

A copper pendant discovered in what is now northern Iraq has been dated about 8700 B.C.