c) Calculate the wave number and wavelength of a ph
oton when the
electron jumps from n2 =4 to ni = 1
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The energy of n
th
level for any atom is determined by the radius and quantum number by:
E
n
=−
2ℏ
2
n
2
Z
2
k
e
2
e
4
m
e
For hydrogen atom the energy varies with shell number as:
E
n
=−13.6
n
2
1
eVEnergy energy released from jump of electron from n=∞ to n=1 is:
E=−13.6(
∞
1
−(
1
2
1
))eV
=13.6eVPhoton of this energy is given by, E=
λ
hc
⟹λ=
E
hc
=91.17nm
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