c-x bond length in halobenzene is small than c-x bond length in ch3-x why
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In halobenzene, halogen atom has lone pair of electrons, which contribute towards the resonance. Out of the five possible resonanting structures, 3 structures have partial double bond which are difficult to break, secondly the carbon attached to the halogen is a sp2 hybridsed carbon, whereas in haloalkanes, carbon is sp3
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In halobenzene there is partial double bond character in C-X bond due to resonance and also C is sp2 hybridised.
While in CH3-X there is only single bond character in C-X bond and C is sp3 hybridised.
This is the reason.
While in CH3-X there is only single bond character in C-X bond and C is sp3 hybridised.
This is the reason.
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