Question

C2H5OH reacts with a mixture of red phosphorus and chlorine to form ____?​

Answer 1

Answer:

ethyl bromide

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Answer 2

Answer:

The Lucas reagent is an aqueous solution of strong acid (HCl) and zinc chloride (ZnCl

2

). Primary alcohols such as ethanol react with Lucas reagent very slowly on heating to give alkyl halide i.e., chloro-ethane.

Ethanol

CH

3

CH

2

OH

+

Conc.

HCl

→

AnhydrousZnCl

2

Chloroethane

CH

3

CH

2

Cl

+H

2

O.

(b) Ethanol when refluxed with PCl

5

forms ethyl chloride.

Ethanol

CH

3

CH

2

OH

+

pentachloride

Phosphorus

PCl

5

→

Ethylchloride

CH

3

CH

2

Cl

+HCl+

oxychloride

Phosphorus

POCl

3

Explanation:

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