C₆H₅NH₂ + CS₂ □(→┴(HgCl₂) )C₆H₅NCS + HgS + 2HCl
the above reaction is:
(a) Libermann’s nitroso reaction
(b) Carbylamine reaction
(c) Hinsberg’s reaction
(d) Hoffmann mustard oil reaction
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Answer:
The answer is _____(d) HOFFMANN MUSTARD OIL REACTION..
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C₆H₅NH₂ + CS₂ □(→┴(HgCl₂) )C₆H₅NCS + HgS + 2HCl is the Hoffmann mustard oil reaction.
Explanation:
Hoffmann mustard oil reaction
- Primary amines of this this reaction, the formation of black precipitate is because of the HgS.
- Primary amine is tested in this reaction.
- It is prepared using alkylisothiocyanide, which is heated with primary amine, carbon disulphied and mercuric chloride.
- Formation of organic base is replaced more than one hydrogen atoms of ammonia in organic groups is the primary amine.
- In the divalent state, mercury chloride contains mercury which denotes the compound as mercury (II) and chlorine is the chemical compound.
- The chemical element which is nonmetallic are carbon disulfide.
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