Calculate AH° for the reaction
2C1F (g) + O2(g) - CIO(g) + OF, (9)
from the following data:
(1) F.(g) + CIF(g) → CIF (1)
AH = - 139.2 kJ
(ii) 2C1F (1) + 20 (9) CLO(g) + 30F,(g) AH = +533.4 kJ
(iii) F (g) + 10 (8) OF (9)
AH° = 24.7 kJ
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O2(g)+O2(g)→O3 ΔH=−107.2KJ/mol
To calculate average bond enthalpy in O3
The equation of the bond enthalpy is
the change in enthalpy of reaction =(the sum of the bonding energy of reactants)-(the sum of the bonding energy of the products)
The change of enthalpy is given as =− 107.2KJ/mol
-107.2KJ/mol =(bond enthalpy sum of reactants)-2(bond enthalpy sum of products)
-107.2KJ/mol = 498.7KJ/mol-2(bond enthalpy of products)
498.7KJ/mol is the BE of O2
its 2 times the bonding enthalpy products because of their 2 kinds of bonds in O3- a single and a double bond
605.9KJ/mol = 2BE
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