Calculate ΔH for the reaction given the following thermochemical equation:
2CO₂+O₂→2CO₂
Clue:C+O₂→CO₂ ΔH= -393.5 Kj/mol
C+1/2 O₂→CO ΔH= -110.5 Kj/mol
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CO₂(g) → CO(g) + ½O₂; Δ H = +294 kJ
That means that we also change the sign of ΔH and divide by 2.
Then we add equations 1 and 3 and their ΔH values.
This gives
C(s) +½O₂(g) → CO(g); Δ H = -99 kJ
Using your numbers, the standard enthalpy of formation of carbon monoxide is -99 kJ/mol.
I think that your value for the heat of combustion of CO is incorrect. It should be -566 kJ.
This would give the correct value of -110 kJ for the heat of formation of CO.
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