Calculate the average internal energy of a diatomic molecule at 300 k using law of equipartition of energy
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The average internal energy of a diatomic molecule is 1.035 × 10⁻²⁰ J.
We have to find the average internal energy of a diatomic molecule at 300K using law of equipartition of energy.
Law of equipartition of energy :
- It states that for any dynamic system in thermal equilibrium, the total energy for the system is equally divided among the degree of freedom.
- The average kinetic energy per degree of freedom is given by, KE = 1/2 KbT.
- average internal energy of a molecule using law of equipartition of energy is given by, E = N × 1/2 KbT., where N is degree of freedom of the molecule.
Here We have to find the average energy of diatomic molecule.
degree of freedom of a diatomic molecule , N = 5
∴ Average internal energy = 5 × 1/2 KbT
= 5 × 1/2 × 1.38 × 10⁻²³ J/K × 300 K
= 1.035 × 10⁻²⁰ J
Therefore the average internal energy of a diatomic molecule is 1.035 × 10⁻²⁰ J.
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