Calculate the concentration of nitric acid in moles per liter in a sample which has a density, 1.41 g M/L and mass percent of nitric acid in it being 69%.
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Answer:
15.44 M
Explanation: Given density of aqueous solution is 1.41 gm/ml of which 69% is nitric acid (HNO3).
So, 69% of 1.41 => 1.41 x 69/100 = 0.9729
Density of Nitric Acid = 0.9729 gm/ml
Now, Density = Mass/Volume. So,
0.9729 = Mass of HNO3/1000ml
Mass of HNO3 = 972.9 gm
No. of moles of HNO3 = Mass of HNO3/Molar mass of HNO3
= 972.9/63
= 15.44 mol.
So Molarity of HNO3 = No. of moles of HNO3/Volume of Solution
= 15.44/1 L
= 15.44 M
(Note) : We find molarity because in the question it is asked to moles per litre which is molarity(M).
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