Calculate the difference between change in enthalpy and
change in internal energy of the system at 300 K for the
following reaction
C(s) + 2H2(g) → CH4(9) (R = 8.314 J/K/mol)
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Answer:
Solution:-
OF2(g)+H2O(g)⟶O2(g)+2HF(g)
ΔHR=∑ΔHf(product)−∑ΔHf(reactant)
∴ΔHR=(2×(−268.6))−(23+(−241.8))
⇒ΔHR=−756kJ/mol
Hence the standard enthalpy change will be −756kJ/mol
Now, as we know that,
ΔH=ΔU+ΔngRT
⇒ΔU=ΔH−ΔngRT
Now from the given reaction,
Δng=nP−nR=(2+1)−(1+1)=1
T=300K(Given)
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