Calculate the dissociation constant of formic acid when it is 4.5% dissociated in a 0.1N solution
at 298 K?
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Answer:
2.1×10
−4
When formic acid is dissolved in water, it partially dissociates (4.5%).
K
a
=
C(1−α)
Cα×Cα
We assume α∼0⇒1−α∼1
⇒K
a
=
1
Cα
2
=0.1×0.045×0.045=2.02×10
−4
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