calculate the energy of kilocalorie per mole of the photon of an electromagnetic radiation of wavelength 5700 angstrom
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λ=7600
A
˚
=7600×10
−8
cm
c=3×10
10
cms
−1
Frequency, v=
λ
c
=
7600×10
−8
3×10
10
=3.947×10
14
s
−1
Energy of one photon =hv=6.62×10
−27
×3.947×10
14
=2.61×10
−12
erg
Energy of one mole of photons =2.61×10
−12
×6.02×10
23
Energy of one mole of photons =2.61×10
−12
×6.02×10
23
=15.71×10
11
erg
Energy of one mole of photons in kilocalorie =
4.185×10
10
15.71×10
11
[1kcal=4.185×10
10
erg]
=37.538 kcal per mol.
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