Chemistry, asked by majedkarzan17, 6 months ago

Calculate the molar solubility of Copper (II) sulfide (Ksp = 6 x 10^-37) in a
solution in which pH is held constant at:
a)2
b)9
Hydrogen sulfide (K1 = 9.6 x 10^-8 & K2 = 1.3 x 10^-14)
(Briefly discuss your results)​

Answers

Answered by SriAchyuth
0

Answer:

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Explanation:

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Answered by sushmaa1912
0

Given:

K_{sp} = 6 \times 10^{-37}

To find:

Molar solubility of CuS

Explanation:

The reaction is give as:

CuS \leftrightharpoons Cu^2^+ + S^2^-

Solubility product equilibrium constant expression is given by:

K_sp = [Cu^2^+][S^2^-]

Let the equilibrium concentration of ions be x M

6 \times 10^{-37} = x^{2}

\sqrt{6\times 10^{-37}} = x = 7.74 \times 10^{-18} M

Therefore molar solubility of CuS = 7.74 \times 10^{-18} M

a) At pH=2 ; which is acidic , the solubility of salt increases due to Le Chateleir principle.

b) At pH=9 ; which is basic, the solubility of salt decreases due to addition  

of OH^-ions and Le Châtelier's Principle says that the position of equilibrium will move to the left.

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