Calculate the % of MnO2 in a sample of pyrolusite ore, 1.5 g which was made to
react with 10 g of Mohr’s salt (FeSO4.(NH4)2SO4. 6H2O) and dilute H2SO4. MnO2 was
converted 2 Mn2+ . After the reaction the solution was diluted to 250 ml and 50 ml of
this solution, when titrated with 0.1 N K2Cr2O7, required 10 ml of the dichromate
solution.
Please answer with explanation.
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Explanation:
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FeSO4 + (NH4)2 SO4 + 6H2O —→ FeSO4 . ( NH4)2 ... 6H2O. Ferrous ammonium sulphate (Mohr's salt) ... solutions of ferrous sulphate and aluminium sulphate in water, 2-3 mL ..
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