Chemistry, asked by priyanshi300503, 9 months ago

calculate the packing efficiency and free space of body centered cubic cell​

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Answered by adityabhandari781
0

The packing efficiency of both types of close packed structure is 74%, i.e. 74% of the space in hcp and ccp is filled. The hcp and ccp structure are equally efficient; in terms of packing. The packing efficiency of simple cubic lattice is 52.4%. And the packing efficiency of body centered cubic lattice (bcc) is 68%.

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Answered by Agamsain
2

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The packing efficiency of both types of close packed structure is 74%, i.e. 74% of the space in hcp and ccp is filled. The hcp and ccp structure are equally efficient; in terms of packing. The packing efficiency of simple cubic lattice is 52.4%. And the packing efficiency of body centered cubic lattice (bcc) is 68%.

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✒ We know that

Packing fraction =

 \rightarrow  \frac{Volume  \: occupied \:  by \:  atoms \:  in \:  a \:  unit \:  cell}{Volume  \: of \:  the  \: unit  \: cell}

For bcc,

Now, substituting the values,

Packing fraction =

  \boxed{  \rightarrow\frac{2 \times  \frac{4}{3}\pi {r}^{3}  }{ {( \frac{4r}{ \sqrt{3} } }^{3} ) } }

 \boxed{ \rightarrow{ \frac{ \sqrt{3\pi} }{8}  = 0.68}}

Volume occupied = 68%

Volume vacant = 100 − 68 = 32%

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