calculate the ph of 0.1 solution of acetic acid. Ka for acetic acid is 1.8 x 10^-5 at 25°C.
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Acetic acid is weak acid
CH3COOH(aq) -----> CH3COO-(aq) + H+(aq)
Ka ( Dissociation constant for acid) represented as
Ka= [CH3COO-] x [H+] / [CH3COOH]
CH3COOHCH3COO-H+Initial conc0.1 00Change in conc-x+x+xequilibrium conc0.1-x+x+x
Ka= [x] [x] / [0.1-x]
1.8 x 10-5 = [x] [x] / [0.1-x]
Now acetic acid is a very weak acid so its extent of dissociation is vey low and x should be neglected from denominator.
Considering the above aspect the obtained equation is given as :
1.8 x 10-5 = [x] [x] / 0.1
x2 = 1.8 x 10-5 x 0.1
= 1.8 x 10-6
x = 1.34 x 10-3 = [H+]
pH= -log[H+]
pH= -log(1.34 x 10-3)
pH= 2.87
pH of 0.1M acetic acid = 2.87
Acetic acid is weak acid
CH3COOH(aq) -----> CH3COO-(aq) + H+(aq)
Ka ( Dissociation constant for acid) represented as
Ka= [CH3COO-] x [H+] / [CH3COOH]
CH3COOHCH3COO-H+Initial conc0.1 00Change in conc-x+x+xequilibrium conc0.1-x+x+x
Ka= [x] [x] / [0.1-x]
1.8 x 10-5 = [x] [x] / [0.1-x]
Now acetic acid is a very weak acid so its extent of dissociation is vey low and x should be neglected from denominator.
Considering the above aspect the obtained equation is given as :
1.8 x 10-5 = [x] [x] / 0.1
x2 = 1.8 x 10-5 x 0.1
= 1.8 x 10-6
x = 1.34 x 10-3 = [H+]
pH= -log[H+]
pH= -log(1.34 x 10-3)
pH= 2.87
pH of 0.1M acetic acid = 2.87
ronilrocky:
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