calculate the wavelength of first spectral of Balmer series for hydrogen. Given that Rydberg constant ,R = 1.097 × 10^7 m^-1.
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The wavelength of photon emitted due to the transition from n to m state of a hydrogen atom is given by
λ
1
=R
H
(
n
2
1
−
m
2
1
)
Let the wavelengths of first and second line of Balmer series be λ
1
and λ
2
respectively.
Now for first wavelength of Balmer series, n=2 and m=3
∴
λ
1
1
=1.097×10
7
(
2
2
1
−
3
2
1
)⟹λ
1
≈6563A
o
For second wavelength of Balmer series, n=2 and m=4
∴
λ
2
1
=1.097×10
7
(
2
2
1
−
4
2
1
)⟹λ
2
≈4861A
o
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