CCL4 is resistant to hydrolysis but SiCl4 is readily hydrolyzed. Why?
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Answer:
lack of d orbital on carbon atom and presence of vacant d orbital on Si atom
Explanation:
At first water molecule attack on vacant 3d orbital of Si and release Cl- and presence of d orbital allow Si to expand its co-ordination number.
But Carbon has no chance for the above 2 cases so inert..
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