Chemistry, asked by satyamkamble567, 5 months ago

CH₂ - C
(CH₂ - CH₂ - CH₂
unstable minor
Arrang the correed order of stability of
falkyle alkyen​

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Answered by muskanjangde861
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Explanation:

(CH₂ - CH₂ - CH₂

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Answered by aparnayadav66
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Answer:

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Contents Home Courses Winona State University Klein and Straumanis Guided 10: Alkynes Expand/collapse global location

10:1 Naming Alkynes

Last updatedJun 6, 2019

10.E: Alkynes (Exercises)

10:2 Alkyne Acidity: Formation of Acetylide Anions

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Objectives

After completing this section, you should be able to

provide the correct IUPAC name of an alkyne, given its Kekulé, condensed or shorthand structure.

provide the correct IUPAC name of a compound containing both double and triple bonds, given its Kekulé, condensed or shorthand structure.

draw the structure of a compound containing one or more triple bonds, and possibly one or more double bonds, given its IUPAC name.

name and draw the structure of simple alkynyl groups, and where appropriate, use these names as part of the IUPAC system of nomenclature.

Study Notes

Simple alkynes are named by the same rules that are used for alkenes (see Section 7.3), except that the ending is -yne instead of -ene. Alkynes cannot exhibit E,Z (cis‑trans) isomerism; hence, in this sense, their nomenclature is simpler than that of alkenes.

Alkynes are organic molecules made of the functional group carbon-carbon triple bonds and are written in the empirical formula of CnH2n−2 . They are unsaturated hydrocarbons. Like alkenes have the suffix –ene, alkynes use the ending –yne; this suffix is used when there is only one alkyne in the molecule.

dicarbon_new_62.png

Introduction

Here are the molecular formulas and names of the first ten carbon straight chain alkynes.

Name

Molecular Formula

Ethyne

C2H2

Propyne

C3H4

1-Butyne

C4H6

1-Pentyne

C5H8

1-Hexyne

C6H10

1-Heptyne

C7H12

1-Octyne

C8H14

1-Nonyne

C9H16

1-Decyne

C10H18

The more commonly used name for ethyne is acetylene, which used industrially.

Naming Alkynes

Like previously mentioned, the IUPAC rules are used for the naming of alkynes.

Rule 1

Find the longest carbon chain that includes both carbons of the triple bond.

Rule 2

Number the longest chain starting at the end closest to the triple bond. A 1-alkyne is referred to as a terminal alkyne and alkynes at any other position are called internal alkynes.

For example:

4-chloro-6-diiodo-7-methyl-2-nonyne

Rule 3

After numbering the longest chain with the lowest number assigned to the alkyne, label each of the substituents at its corresponding carbon. While writing out the name of the molecule, arrange the substituents in alphabetical order. If there are more than one of the same substituent use the prefixes di, tri, and tetra for two, three, and four substituents respectively. These prefixes are not taken into account in the alphabetical order.

For example:

2,2,10-triiodo-5-methyldec-3-yne_new_301.png

1-triiodo-4-dimethyl-2-nonyne

If there is an alcohol present in the molecule, number the longest chain starting at the end closest to it, and follow the same rules. However, the suffix would be –ynol, because the alcohol group takes priority over the triple bond.

5- methyl-7-octyn-3-ol

When there are two triple bonds in the molecule, find the longest carbon chain including both the triple bonds. Number the longest chain starting at the end closest to the triple bond that appears first. The suffix that would be used to name this molecule would be –diyne.

For example:

4-methylocta-1,5-diyne_new_228.png

4-methyl-1,5-octadiyne

Rule 4

Substituents containing a triple bond are called alkynyl.

For example:

1-chloro-1-ethynyl-4-bromocyclohexane

Here is a table with a few of the alkynyl substituents:

Name

Molecule

Ethynyl

-C≡CH

2- Propynyl

-CH2C≡CH

2-Butynyl

-CH3C≡CH2C

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