Question

CH3NH2 is more basic than C6H5NH2.​

Answer 1

Answer:

CH3NH2 is more basic than C6H5NH2.

Explanation:

On the other hand, in aniline lone pair of electron on the nitrogen atom is delocalised over the benzene ring due to resonance and thus making it less available for donation. That is why CH3−NH2 is more basic than C6H5−NH2.

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Answer 2

Note: The correct question must be-

$CH_{3}NH_{2}$ is more basic than $C_{6}H_{5} NH_{2}$.

Give reason.

1. The $+I$ effect of the $CH_{3}$ group increases the electron density on the $N$ atom in $CH_{3}NH_{2}$, making the lone pair more available for donation.
2. In aniline, on the other hand, the lone pair of electrons on the nitrogen atom are delocalised over the benzene ring due to resonance, making it less available for donation.
3. Hence, CH3 NH2 is more basic than C6H5NH2.

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