Chemical test to distinguish between propan-2-ol and 2-methyl-2-propan-2-ol
Answers
Let’s look at the structure of Propan-1-ol and 2-methyl propan-2-ol,
This is Propan-1-ol or generally known as Propanol.
The carbon atom to which the alcoholic functional group is attached is a [math]1^o [/math]Carbon atom or a Primary Carbon atom, i.e it is linked to a single carbon atom only.
While,
this is 2-methyl propan-2-ol.
The carbon atom to which the alcoholic functional group is attached is a [math]3^o[/math][math] [/math]Carbon atom or a Tertiary Carbon atom, i.e it is linked to three carbon atoms.
Now this is how we can distinguish them on their structure, but if it was a CHEMICAL DISTINGUISHING TEST you’re seeking, then we can actually use Luka’s Test to distinguish between them.
Now coming to what is Luca’s Test,
Luca’s test includes a reaction between an alcohol with a Halogen hydride and it’s Zinc salt.
Now the reason we can use this for our benefit is that,
[math]1^o [/math]Carbon atoms or Primary carbon atoms undergo the reaction very fast and white fumes of Haloalkanes appear inside the flask or test tube.
[math]2^o [/math]Carbon atoms or Secondary carbon atoms undergo the reaction at a slow rate and the fumes appear after a brief interval of time.
While [math]3^o [/math]Carbon atom or a Tertiary Carbon atom won’t undergo the reaction until and unless the reaction mixture is heated.
So, Propan-1-ol and 2-methyl propan-2-ol can be distinguished using Luca’s test as Propan-1-ol would give white fumes very easily while 2-methyl propan-2-ol won’t form any fumes until the reaction mixture is heated.
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That's a Iodoform test
Refer to the attachment!!