Question

chemistry:

out of chlorobenzene and benzyl chloride which one gets easily hydrosyled by aqueous NaOH and why ?

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Answer 1

Answer:

Benzyl chloride get easily hydrolysed by aq NaOH due to stable benzyl carbonation But due to partial double bond character of c-cl bond in chlorobenzene it does not hydrolyse.

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Answer 2

solution

in chlorobenzene there is partially double character.so by SN2 mechanism it is easy to OH-

group to substitute .

but in case of benzyl chloride , oh - subsitute by

SN2 mechanism, due to formation of stable benzyl chloride carbonation.

so benzyl chloride gets easily hydrosyled.