Compare rate of reaction with AgNO3 :
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Order of rate of reaction with AgNO
3
or rate of S
N
1 is 1 > 3 > 2
SN
1
reaction prefer tertiary alkyl halide as it proceeds with formation of carbocation as an intermediate.
Here carbocation formed in the compound I will be more stable than the other compound as the compound I has pi electrons to stabilize it.
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