Compare the electrolysis of molten potassium chloride and solution of potassium chloride. What are the processes taking place at the cathode and the anode?
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when molten kcl
k+ and cl-
At Cathode:-
K+e-=K
At Anode:-
2cl- =2cl+2e-
When solution of Kcl then discharge potential method works
K+ cl- H+ Oh-
At anode:-
2cl- =cl2 +2e-
At cathode:-H20+e- = H2 + Oh-
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