Compare the stability of oxidation states
of 3d series elements with those of 4d
and 5d series elements.
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through current that have
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The comparison of stability of oxidation states of transition series :
- The oxidation state of the 3d series is lesser than that of 4d and 5d series. There are 3 transition series in the d block .
- The oxidation state is increases down the series, means 3d have less O.S than 4d and 5d .
- 3d series:
- As comparative to 4d and 5d series they have small size and in this the low oxidation state is more stable like +2 and +3 .
- Example : Co form many stable complexes with +2 and , +3 and same Fe also can form. But in the 4d and 5d series like Rh, It they are unable to form stable complexes in this oxidation state.
- Here , in group 9 Co shows +2 and +3 O.S and in group 8 Fe also show this valency . +3 is the highest valency in this series .
- 4d and 5d series :
- In this due to lanthanoid contraction the size of elements is similar in both the series. Here the , high oxidation number is more stable.
- Example : Rh , Os show +4,+6,+8 oxidation state . So, here the highest oxidation state is+8.
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