Complete the following analogy:
NH3 : A: : H2O : B
(a) A: Lone pair – lone pair repulsion B: Lone pair-bond pair repulsion only (b) A: sp3 hybridisation B: sp2 hybridisation (c) A: Two lone pairs of electrons B: One lone pair of electrons (d) A: Trigonal pyramidal B: Bent
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- Determine the number of lone pairs on the central atom in the molecule, and add the number of bonded atoms (a.k.a. bonding domains)
- This number (the steric number) defines the electronic shape of the molecule by minimizing repulsion. For example a steric number of three gives a trigonal planar electronic shape.
- The angles between electron domains are determined primarily by the electronic geometry (e.g., 109.5° for a steric number of 4, which implies that the electronic shape is a tetrahedron)
- These angles are adjusted by the hierarchy of repulsions: (lone pair - lone pair) > (lone pair - bond) > (bond - bond)
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