complete the following reaction and predict the optical acrivity of the products formed pent-1-ene with HBr
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Explanation:
Normally, reacting HBr with an alkene will result in the Markovnikov product, meaning the the bromide will bond to the most substituted carbon, and the hydrogen will bond to the least substituted carbon. In the case of 1-pentene, addition of HBr would result in 2-bromopentane,
However, in the presence of peroxides, reaction of an alkene with HBr will result in the anti-Markovinkov product, 1-bromopentane:
This is known as the peroxide effect.
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