Confirmation of particle nature of radiation was provided by compton effect.
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Particle nature of radiation is directly confirmed by Compton effect.
A free electron cannot exhibit photoelectric effect because photoelectric effect provides evidence that energy is quantized i.e. to restrict the possible values of (a magnitude or quantity) to a discrete set of values by quantum mechanical rules.
Photons carrying momentum is a necessary condition in order to establish the particle nature of radiation.
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