Question

Consider the compounds, $BCl_{3}$ and $CCl_{4}$. How will they behave with water? Justify.

Answer 1

$BC{ l }_{ 3 }$  reacts with water to form boric acid and it easily undergoes hydrolysis being a Lewis acid.

$BC{ l }_{ 3 }\quad +\quad 3{ H }_{ 2 }O\quad \rightarrow \quad 3HCl\quad +B(OH{ ) }_{ 3 }$

But $CC{ l }_{ 4 }$ do not undergoes hydrolysis because of lack of vacant orbital in carbon atom. Therefore, it does not readily accept the electrons from the water to form an intermediate.

If we mixed $CC{ l }_{ 4 }$ with ${ H }_{ 2 }O$ to form two different layer. Therefore, these are called as immiscible liquids.

$C{ Cl }_{ 4 }\quad +\quad { H }_{ 2 }O\quad \rightarrow \quad No\quad reaction.$

Answer 2

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